Interfacial Self-assembly of Silk Fibroin Polypeptide and ?-NiCo(OH)2 Nanocrystals with Tunable Energy Storage Applications

  • Autor
  • Eduardo R. do Nascimento
  • Co-autores
  • Wendel A. Alves , Barbara B. Gerbelli , Fabio F. Ferreira
  • Resumo
  • There is an increasing interest in the self-assembly process from a bottom-up approach to synthesizing functional structures for engineering applications. Silk fibroin is a protein extracted from the cocoons of silkworm Bombyx mori that can be processed into various materials generally stabilized by the induction of ?-sheet formation through solvents or by physical stretching. In our study, the introduction of cobalt-substituted nickel hydroxide nanoparticles on silk fibroin presented a dual effect, causing the stabilization of the ? polymorph of nickel hydroxide and promoting a highly connected network of the ?-sheet crystalline domain in the fibroin chains. Electrochemical measurements were performed to examine silk fibroin (SF)/NiCo(OH)2 hybrid materials. The optimized sample exhibits a high specific capacity of 362 mA h g-1 at the current density of 1 A g-1, maintaining steady electrochemical performance >75% of the initial value at higher current densities. The presented assembly provides a route for preparing monodisperse inorganic nanoparticles in the presence of SF as an organic matrix with potential energy storage properties. 

  • Palavras-chave
  • silk fibroin, nickel hydroxide, energy storage, self-assembly
  • Modalidade
  • Pôster
  • Área Temática
  • Nanociência e Nanotecnologia
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Bem-vindo(a) aos Anais do VII NanoMat, evento organizado pela Pós-graduação em Nanociências e Materiais Avançados da Universidade Federal do ABC (UFABC) com o intuito de reunir e debater trabalhos desenvolvidos por alunos e pós-doutorandos em Materiais e áreas afins.

  • Nanociência e Nanotecnologia
  • Materiais Funcionais Avançados

Comissão Organizadora

Pedro Alves da Silva Autreto
Andre Luiz Martins de Freitas
Aryane Tofanello

Comissão Científica